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Properties of Pure Substances

صفحه 1:
en KC) ‏ای‎ 9

صفحه 2:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. FIGURE 2-11 T-v diagram for the heating T°C process of water at constant pressure. 300 Saturated 100 mixture

صفحه 3:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 6 Critical point 374.14) ١ Saturated Saturated vapor liquid 0.003155 ani FIGURE 2-16 T-v diagram of constant- pressure phase-change processes of a pure substance at various pressures (numerical values are for water). 2-2

صفحه 4:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or ‘display. Critical 5 point ‏ار‎ 7 ‏ی‎ ‏ور‎ ‎4 ‏رخني‎ ‎we £ COMPRESSED ‏ف‎ 0 LIQUID Se REGION / SUPERHEATED VAPOR 7 REGION SATURATED 2 LIQUID-VAPOR 3 REGION ey FIGURE 2-18 T-v diagram of a pure substance. 2-3

صفحه 5:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. FIGURE 2- 19 iB P-v diagram 9 of a pure \ cecal substance. 1 5 ۱ \ \ ۱ SUPERHEATED ۱ VAPOR ۱ COMPRESSED| LIQUID 3 REGION ۲ SATURATE LIQUID-VAPOR REGION 2-4

صفحه 6:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or FIGURE 2-21 display. ۲-۷ ofa 2 substance that contracts on freezing. Critical point VAPOR SOLID SOLID + LIQUID LIQUID + VAPOR ‘Triple line SOLID + VAPOR 2-5

صفحه 7:
FIGURgygight © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Critical point VAPOR LIQUID + VAPOR ‘Triple line SOLID + VAPOR SOLID 22 P-v diagram of a substance that expands on freezing (such as water). 2-6

صفحه 8:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. FIGURE 2- ‏م‎ ‎25 Substances Substances P-T diagram , that expand that contract of pure ‏سب‎ on freezing ۱ we substances. Critical point “Triple point VAPOR 2-7

صفحه 9:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or FIGURE 2-26 P-v-T surface of a substance that contracts on freezing. 2 Z 3 2

صفحه 10:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or displav. FIGURE 2-27 P-v-T surface of a substance that expands on freezing (like water). Pressure

صفحه 11:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or displav. Specific volume 3 Sat. He Temp. press | Sat. Sat. 2 kPa liquid vapor 1 Pay 7 ‏ول‎ ‎85 57.83 0.001 033 8 90 70.14 ۱0.001 036 1 95 84.55 1 2 Specific Specific temperature volume of saturated liquid Corresponding Specific saturation volume of pressure saturated vapor FIGURE 2- 30 A partial list of Table A-4.

صفحه 12:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 4, 1 h, m/kg ki/kg ۶۵ P =0.1 MPa (99.63°C) 1.6940 2506.1 2675.5 1.6958 2506.7 2 1.9364 2582.8 2776.4 7.260 4683.5 5 P = 0.5 MPa (151.86°C) 0.3749 2561.2 2748.7 0.4249 2642.9 2855.4 0.4744 2723.5 2960.7 Bee. Sat. 100 150 1300 Sat. 200 250 FIGURE 2-40 A partial listing of Table A-6.

صفحه 13:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or displav. ne FIGURE 2-49 ‘ook ‏تو ا مزهو‎ ۳ ap 5 Percentage of error involved in assuming steam to be an ideal gas, and the region where steam can be 400 treated as an ideal gas with less than 1 percent error. 200) 10 212 ۲ mig

صفحه 14:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. FIGURE 2-51 Comparison of Zfactors "' for various ‘a a gases. ‏اده‎ ‎۱ | ‏اه‎ ‎a ag oa Legend % Mothane ‏و‎ مسد ع ‎Eihylene‏ © 03 ‎Nitrogen‏ 4 مناد © Propane © Carbon dioxide ‏مين * م5‎ ۳ Average curve based on data on ‏سم د‎ on 0 ا كك م 15 16 55 06 2-3

صفحه 15:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display. FIGURE 2-60 Percentage [ov Van be West op) of error “ ons Bouse No Re som) involved in various one equations of 58 state for nitrogen. an $ ‏ول‎ hax é ‏ار‎ Sat han & ‏سد‎ / 05 Ban 1 ie ite 2-14

صفحه 16:
Copyright © The McGraw-Hill Companies, Inc. Permission required for reprodu 5 displav. FIGURE 2-68 5 78 Ideal-gas ar constant- 60 pressure specific heats for some gases (see Table A-2c 50 for C,, equations). 20 1000 2000 3000 2-15 ‘Temperature, K

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