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* w

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Medicinal Plants Reading: Textbook, | Chapter 11 Ng ‘i 4 2 9

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Margarine - made from fats - originally from animal fats - white in color, so yellow dye added to create appearance of butter Advantage: Stores better than butter Dairy Industry - fought against use of margarine - Taxes - Regulations against sale; against use of dyes Wisconsin - prohibited sale of colored margarine- Repealed 1967; + heavy tax on uncolored (white) margarine (people would buy and mix their own coloring agent)

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Quiz

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Quiz 1.Name two of the four major vegetable oil crops. 2.Name a medicinal plant, and tell what medicine is obtained from it and a disease it is used to treat 3.What does soap have to do with vegetable oil?

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History - Highlights 2500 BC - Sumerian use of opium popp 0 11.2, p.

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History - Highlights 2500 BC - Sumerian use of opium popp 0 11.2, p. 1770 BC - Code of Hammurabi in Babylon - mentions plants

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History - Highlights 2500 BC - Sumerian use of opium pens >: | 1770 BC - Code of Hammurabi in Babylon - mentions plants 1550 BC - Ebers papyrus in Egypt - 700+ medicinal formulas

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History - Highlights 2500 BC - Sumerian use of opium pens >: | 1770 BC - Code of Hammurabi in Babylon - mentions plants 1550 BC - Ebers papyrus in Egypt - 700+ medicinal formulas 400 BC - Hippocrates (Greece) - “Father of Medicine” 300 BC - Theophrastus, Botanical Gardens in Athens

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History - Highlights 2500 BC - Sumerian use of opium popp ۳ 11.2, ۰ 1770 BC - Code of Hammurabi in Babylon - mentions plants 1550 BC - Ebers papyrus in Egypt - 700+ medicinal formulas 400 BC - Hippocrates (Greece) - “Father of Medicine” 300 BC - Theophrastus, Botanid Athens 77 AD - Dioscorides, De Materij

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History - Highlights 2500 BC - Sumerian use of opium pens >: | 1770 BC - Code of Hammurabi in Babylon - mentions plants 1550 BC - Ebers papyrus in Egypt - 700+ medicinal formulas 400 BC - Hippocrates (Greece) - “Father of Medicine”

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History - Highlights II 1500 AD - Age of herbalism, Paracelsus - Doctrine of Signatures

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History - Highlights II 1500 AD - Age of herbalism, Paracelsus - Doctrine of Signatures

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History - Highlights II 1500 AD - Age of herbalism, Paracelsus - Doctrine of Signatures 1775 AD - Dr. William Withering - Foxglove extracts 1900 AD - Half of drugs in U.S. Pharmacopeia still derived directly from plants

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History - Highlights II 1500 AD - Age of herbalism, Paracelsus - Doctrine of Signatures 1775 AD - Dr. William Withering - Foxglove extracts 1900 AD - Half of drugs in U.S. Pharmacopeia still derived directly from plants 1900s - advent of “scientific medicine”

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History - Highlights II 1500 AD - Age of herbalism, Paracelsus - Doctrine of Signatures 1775 AD - Dr. William Withering - Foxglove extracts 1900 AD - Half of drugs in U.S. Pharmacopeia still derived directly from plants 1900s - advent of “scientific medicine” 1 NGCAM National Center for Complementary and Alternative Medicine The National institutes of Health

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Plant-Derived Medicines Major Classes of Compounds: 1. Steroids

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Plant-Derived Medicines Major Classes of Compounds: 1. Steroids 2. Alkaloids

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Plant-Derived Medicines Major Classes of Compounds: 1. Steroids 2. Alkaloids Useful terms: “Secondary Compound” “Glycoside”

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Steroids - Chemistry Fig: 11.5;'p: eit 4 Steroid ring system

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Steroids - Chemistry HO. holest 4 Steroid ring system 5 (Cholesterol)

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Steroids - Chemistry OT gi ‎cholic wid (eee) Cortisens onentnaraton‏ و0 ‎tenn‏ اممو ‎ ‎

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Alkaloids - Chemistry 1. Organic compound, with N, usually in ring structure Fig: 11.7; 'p: 272

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Alkaloids - Chemistry . Organic compound, with N, usually in ring structure . Physiologically active on vertebrate systems

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Alkaloids - Chemistry 1. Organic compound, with N, usually in ring structure 2. Physiologically active on vertebrate systems > Diverse. |. 1 55 Hs 1 Goniine (1) Nicotine @)

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Alkaloids - Chemistry 1. Organic compound, with N, usually in ring structure 2. Physiologically active on vertebrate systems > Diverse. |. 1 55 1 ‏کمن‎ oO 0 Goniine (1) Nicotine @) lOO a ‏بط‎ Reserpine Vinbastine Strychnine 4, “come

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Examples of Plant Medicine 276 1900 - over half of drugs in U.S. Pharmacopeia from plants 2001 - about 25% of drugs in U.S. Pharmacopeia from plants, but many synthetic compounds are based on plant-produced structures, or start with plant materials Anasthetics, analgesics, heart medicines, laxatives, muscle relaxants etc.

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Chaulmoogra Oil - Hydnocarpus Leprosy - bacterial disease, affects sensitive individuals ingredient - seed oil Now replaced with و یی ‎antibiotics‏

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Malaria - Cinchona Malaria - caused by protozoan cinchona = = ‘eal 5 Bark”

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Cinchona - “bark of Peru”; ”yellow bark” About 40 species - Andean area of South America

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Salix - Aspirin Hippocrates (Greece) - used willow bark to treat pain

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Salix - Aspirin Hippocrates (Greece) - used willow bark to treat pain 1897 - Bayer Co. (Germal 14,

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Salix - Aspirin Hippocrates (Greece) - used willow bark to treat pain 1897 - Bayer Co. (Ge 7 4,

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Dioscorea steroids Wild Yam - convenient source for steroidal saponins which can be converted into synthetic hormones for use in contracep ig. 11.13,p 277 Diosgenin Detiydropreguenol one acctate Eragesterone

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Papaver Alkaloids

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۲2۱۶41 ‏ا نتنا د ل١ل] - تالا‎ child for plant-derived ۳ ——medicipe tHective ‏کح وو تسیل‎ lymphomas (Hodgkin’s disease) ۷۵ ان Vinbiastine

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New Drug Development average to develop a new drug in U.S. - $231 million/12 years -> many not developed, if patent protection not available, or if market not assured Comparison: Germany - "reasonable certainty" of safety and effectiveness U.S. - “absolute proof" -> some modern herbal preparations coming from Europe, sold as dietary supplements in U.S. Examples: St. John's Wort, Echinacea, Gingko

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Looking for new drugs - General parameters: 1 in 10,000 chemicals screened -> new drug product Development of new drug in U.S. - 12 years/$231 million (average) Many drugs/diseases - not pursued because of lack of profitability

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Development of Phy 906 - Phytoceutica Herbal medicine Based on Chinese Traditional Medicine Mixture of herbs: scutellaria (skullcap), glycyrrhiza (licorice), ziziphus (jujube), Paeonia (peony) Application: treat nausea and pain associated with cancer chemotherapy regimes Initial results: not only effective against side effects, but also appears to increase efficacy of chemotherapy for certain cancers

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Problems in Development of Rain Forest Drugs International Agreements (1) Discovery - by pharmaceutical companies - preceded by traditional healers Who discovered/Who should benefit financially? (2) Ownership - seeds, genes, chemicals cycle: Gene poor country, has scientific expertise -> Gene rich country, has genetic diversity but lacks science -> development of chemical by gene poor country -> now sell back to gene rich/economically poor country

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SSS a ‏تا‎ Psychoactive and Poisonous nts Reading: Textbook, Chapter 12

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